Manufacture of Acids and Bases

Manufacture of acids and bases

a) Nonmetal oxide + water → acid

SO2(g) + H2O(l) → H2SO3(aq)
SO3(g) + H2O(l) → H2SO4(aq)
4NO2(g) + 2H2O(l) + O2(g) → 4HNO3(aq)

Non-metal oxides are thus referred to as acid anhydrides.

b) Hydrogen + halogen → acid

H2(g) + Cl2(g) → 2HCl(g)
HCl(g) + H2O(l) → HCl(aq)

c) Metallic salt + conc. sulphuric acid → salt + more volatile acid
2NaCl(aq) + H2SO4(aq) → Na2SO4(aq) + 2HCl(aq)
2KNO3(aq) + H2SO4(aq) → K2SO4(aq) + 2HNO3(aq)

d) Metal + oxygen → metallic oxide (base)
4Na(s) + O2(g) → 2Na2O(s)
2Mg(s) + O2(g) → 2MgO(s)

e) Metal + water → base or alkali + hydrogen
Zn(s) + H2O(steam) → ZnO(s)+ H2(g)

f) Few metallic oxides + water → alkali
Na2O(s) + H2O(l) → 2NaOH(aq)

g) Ammonia + water → ammonium hydroxide
NH3(g) + H2O(l) → NH4OH(aq)

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