Formula and Derivation

Gay-Lussac’s law implies that the ratio of the initial pressure and temperature is equal to the ratio of the final pressure and temperature for a gas of a fixed mass kept at a constant volume. This formula can be expressed as follows:

(P1/T1) = (P2/T2)

Where:

  • P1 is the initial pressure
  • T1 is the initial temperature
  • P2 is the final pressure
  • T2 is the final temperature

This expression can be derived from the pressure-temperature proportionality for gas. Since P ∝ T for gases of fixed mass kept at constant volume:

P1/T1 = k (initial pressure/ initial temperature = constant)

P2/T2 = k (final pressure/ final temperature = constant)

Therefore, P1/T1 = P2/T2 = k

Or, P1T2 = P2T1

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